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Examples
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What you find is that if you try to measure chroma, as defined by munsell, on the CIE space, you'll find that chroma depends both on lightness and saturation, growing with both.
Peak Saturation Value James Gurney 2010
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Then you just re-scale according to perceptual differences, and get a munsell renotation in this news space.
Charting Pigments James Gurney 2010
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My problem with the usual explanations of the munsell system stems from this:
Peak Saturation Value James Gurney 2010
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Development of the 1929 munsell book of color: A historical review
Peak Saturation Value James Gurney 2010
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It will be...hem... a bit harder to do a munsell "sphere" or catalog though :D
Charting Pigments James Gurney 2010
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