Definitions

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  • n. any derivative of a thiol in which a metal atom replaces the hydrogen attached to sulfur RSH => RS-M+

Etymologies

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Examples

  • Here, we present a new disulfide/thiolate redox couple that has negligible absorption in the visible spectral range, a very attractive feature for flexible DSCs that use transparent conductors as current collectors.

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  • Now, a team led by Gr├Ątzel, who is at the Swiss Federal Institute of Technology in Lausanne, has demonstrated a new electrolyte based on a disulfide/thiolate redox couple using

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  • In this study, we employ the two above-mentioned heme-thiolate proteins to probe the reaction kinetics and mechanism of heme enzymes.

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  • (6Z,8E,10E,14Z) - (5S,12R) - 5,12,20-trihydroxyicosa-6,8,10,14-tetra - enoate + NADP+ + H2 O (a heme-thiolate protein P450; not identical with EC 1.14.13.34) Reaction type w-oxidation redox reaction reduction Natural substrates and products S

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  • Svendsen, I.; Moller, B.L.: Isolation and reconstitution of the heme-thiolate protein obtusifoliol 14a-demethylase from Sorghum bicolor (L.)

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  • (, possibly a heme-thiolate protein [1-3]) [1-3] Additional information

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  • < 1, 2 > (heme-thiolate protein, 0. 2-0.9 nmol per mg protein [1]) [1-3] 474

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  • (heme-thiolate protein, 0. 2-0.9 nmol per mg pro - tein [1]) [1] Activating compounds FAD

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  • + 3 NADP+ + 3 H2 O (The heme-thiolate enzyme, P - 450, catalyses successive hydroxylations of the 14a-methyl group and C-15, followed by elimination as formate leaving the 14 (15) double bond.

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