azide

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Quantum chemical calculations predict that the S2 state of the azide is bound and that there is a much lower barrier toward arylnitrene formation from the S1 state of the azide.

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Definitions (4)

Toggle American Heritage definitions American Heritage Dictionary (1)

  1. noun A chemical compound that contains the group N3.

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Examples (43)

  • Its solid matter with m.p. 23C. Take into account that common organic azide-ethyne reaction condensation works at higher temperatures. —  The Explosives and Weapons Forum: medina?
  • Photolysis of phenyl and o-biphenylyl azide (at 270 nm) releases vibrationally excited singlet nitrene which isomerizes to the corresponding hot 1,2-didehydroazepine at a rate competitive with thermal relaxation. —  CiteULike: Everyone's library
  • The photochemistry of ortho-biphenyl azide (1a) has been studied by laser flash photolysis —  CiteULike: Everyone's library
  • The photochemistry of para - and ortho-biphenylyl azides and 1-naphthyl azide was studied by ultrafast spectroscopy. —  CiteULike: Everyone's library
  • Quantum chemical calculations predict that the S2 state of the azide is bound and that there is a much lower barrier toward arylnitrene formation from the S1 state of the azide. —  CiteULike: Everyone's library
 

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